Munzur ÜniversitesiMunzur ÜniversitesiAçık Erişim Arşivi · RDL Open

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  • MakaleYalnız künye2024Scopus SJRQ3
    Powder coating waste filler in high-density polyethylene – Variations in morphology, mechanical and thermal performance; [Variationen in Morphologie, mechanischer und thermischer Leistung von Pulverlackrecyclaten als Füllstoff in Polyethylen mit hoher Dichte]

    Kısmet, Y.

    In the present study, electrostatic powder coating waste was recycled and employed to reinforce high-density polyethylene. The hydrolysis method was preferred to modify the powder coating waste of various systems, and they were mixed with high-density polyethylene at various weight ratios. The mixtures were prepared in a mechanical mixer and then in an extruder to obtain a homogeneous mixture. This homogeneous structure was pressed into molds with a plastic injection device to obtain standard tensile samples. Mechanical and thermal tests were conducted on the samples. It was determined that the tensile stress of the sample decreased with the increase in filler content. The changes in sample tensile strength were investigated after the samples were aged. Three-point bending strength of the samples was also investigated and it was observed that they became more resistant to vertical loads as the filler content increased. The Izod impact strength of the samples differed based on the filler type and weight ratio. Furthermore, mass loss in the produced mixtures was determined with thermogravimetric analysis. The matrix and filler bonding mechanisms were observed under an electron microscope.

    • SDG 9 · Sanayi, Yenilikçilik ve Altyapı
    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus1WoS1OpenAlex1
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2024Scopus SJRQ1
    Novel formulations ameliorate osteoarthritis in rats by inhibiting inflammation and oxidative stress

    Erten, Fusun; Ozdemir, Oguzhan; Tokmak, Muhammed; Durmus, Ali Said; Ozercan, Ibrahim Hanifi; Morde, Abhijeet; Padigaru, Muralidhara; Sahin, Kazim

    The study tested new oral plant-based formulations (F) on rats with monosodium iodoacetate (MIA)-induced osteoarthritis, measuring inflammation, antioxidant levels, paw size, stride, and analyzing knee joint images. Fifty-six female Sprague Dawley rats were allocated into 8 groups: (1) Control, (2) MIA (OA induced with MIA), (3) MIA + F1 [curcuminoids+gingerols+acetyl-11-keto-β boswellic acid (AKBA)], (4) MIA + F2 (curcuminoids+Withania glycosides+AKBA), (5) MIA + F3 (curcuminoids+total withanolides+AKBA), (6) MIA + F4 (curcuminoids, AKBA), (7) MIA + UCII (type II collagen), and (8) MIA + GCHON (Glucosamine Chondroitin). Treatments F1 to F4 reduced right joint diameter and improved stride length and paw area in OA rats. Despite improvements with treatments F1 to F4, there was no significant difference between these groups (p >.05). In OA animals, F1 to F4 treatments decreased MDA levels and increased antioxidant enzymes activities (p <.001). This was done by reducing levels of inflammatory markers and enzymes like IL-1β, IL-6, MMP-8, TNF-α, CRP, COMP, and LOX-5, while increasing the anti-inflammatory cytokine IL-10. In conclusion, these plant-based treatments significantly reduced osteoarthritis severity, slowed disease progression by reducing inflammation, and protected joints from damage, showing a protective effect in rats with induced osteoarthritis, likely due to their anti-inflammatory and antioxidant properties.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus14WoS11OpenAlex10
    ScopusWeb of SciencePubMedİncele
  • MakaleYalnız künye2024Scopus SJRQ3
    Functionalized and Ag-Loaded Nano-Delivery System for Doxorubicin: Loading, Controlled Release and Kinetic Studies

    Aydogdu, Burcu; Kaplan Ince, Olcay; Ince, Muharrem; Unal, Ilkay

    Multi-walled carbon nanotubes (fMWCNTs) that functionalized and loaded Ag nanoparticles (AgNPs) were investigated to adsorp doxorubicin hydrochloride (DXR). DXR release behavior efficiency was determined using kinetic studies. DXR agent was treated into fMWCNTs@AgNPs material with different drug loading rates. The material was successfully established and characterized using transmission electron microscopy, and fourier transform–infrared spectroscopy. Thermogravimetric analysis was performed to elucidate the effect of temperature on mass loss and X-ray diffraction analysis was systematically assessed the crystalline state of DXR. Various kinetic models including Higuchi, Baker Hixson-Crowell, and power-law were applied. It was revealed that DXR has more binding affinity to the fMWCNTs@AgNPs material system surface as a nanocarrier at pH 7.4 and showed more release at pH 5.0. Functionalized material confirmed its efficiency as pH-based drug delivery system. Used material can be utilized as promising nanocarriers, and findings will contribute to the rational design of novel delivery tools for drugs.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2024Scopus SJRQ2
    Uncovering chemical profiles, biological potentials, and protection effect against ECM destruction in H2O2-treated HDF cells of the extracts of Stachys tundjeliensis

    Kurt-Celep, Inci; Zheleva-Dimitrova, Dimitrina; Sinan, Kouadio Ibrahime; Uba, Abdullahi Ibrahim; Nilofar; Mahomoodally, Mohamad Fawzi; Aumeeruddy, Muhammad Zakariyyah; Cakilcioglu, Ugur; Dall'Acqua, Stefano; Zengin, Gokhan

    The genus Stachys L., one of the largest genera of the Lamiaceae family, is highly represented in Turkey. This study was conducted to determine the bio-pharmaceutical potential and phenolic contents of six different extracts from aerial parts of Stachys tundjeliensis. The obtained results showed that the ethanol extract exhibited the highest antioxidant activity in the antioxidant assays. Meanwhile, the ethanol extract displayed strong inhibitory activity against α-tyrosinase, the dichloromethane extract exhibited potent inhibition against butyrylcholinesterase, and the n-hexane extract against α-amylase. Based on ultra-high performance liquid chromatography coupled to high-resolution mass spectrometry analysis, more than 90 secondary metabolites, including hydroxybenzoic acid, hydroxycinnamic acid, and their glycosides, acylquinic acids, phenylethanoid glycosides, and various flavonoids were identified or tentatively annotated in the studied S. tundjeliensis extracts. It was observed that the application of S. tundjeliensis eliminated H2O2-induced oxidative stress. It was determined that protein levels of phospho-nuclear factor kappa B (NF-κB), receptor for advanced glycation endproducts, and activator protein-1, which are activated in the nucleus, decreased, and the synthesis of matrix metalloproteinase (MMP)-2 and MMP-9 also decreased to basal levels. Overall, these findings suggest that S. tundjeliensis contains diverse bioactive compounds for the development of nutraceuticals or functional foods with potent biological properties.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus12OpenAlex12
    ScopusWeb of SciencePubMedİncele
  • MakaleAçık Erişim2024Scopus SJRQ2
    Combining chemical profiles and biological abilities of different extracts from Tanacetum nitens (Boiss. & Noë) Grierson using network pharmacology

    Dall'Acqua, Stefano; Yagi, Sakina; Sut, Stefania; Uba, Abdullahi Ibrahim; Ponniya, Sathish Kumar M.; Koyuncu, Ismail; Toprak, Kenan; Balos, Mehmet Maruf; Kaplan, Alevcan; Çakılcıoğlu, Uğur

    Tanacetum nitens (Boiss. & Noë) Grierson is an aromatic perennial herb used in Turkish traditional medicine to treat headache, fever, and skin diseases. This study aimed to investigate the chemical composition, antioxidant, enzyme inhibition, and cytotoxic properties of T. nitens aerial parts. Organic solvent extracts were prepared by sequential maceration in hexane, dichloromethane, ethyl acetate, and methanol while aqueous extracts were obtained by maceration or infusion. Nuclear magnetic resonance (NMR) and LC-DAD-MS analysis allowed the identification and quantification of different phytoconstituents including parthenolide, tanacetol B, tatridin B, quinic acid derivatives, β-sitosterol, and glycoside derivatives of quercetin and luteolin. The type and amount of these phytochemicals recovered by each solvent were variable and significant enough to impact the biological activities of the plant. Methanolic and aqueous extracts displayed the highest scavenging and ions-reducing properties while the dichloromethane and ethyl acetate extracts exerted the best total antioxidant activity and metal chelating power. Results of enzyme inhibition activity showed that the hexane, ethyl acetate, and dichloromethane extracts had comparable anti-acetylcholinesterase activity and the latter extract revealed the highest anti-butyrylcholinesterase activity. The best α-amylase and α-glucosidase inhibition activities were obtained from the hexane extract. The dichloromethane and ethyl acetate extracts exhibited the highest cytotoxic effect against the prostate carcinoma DU-145 cells. In conclusion, these findings indicated that T. nitens can be a promising source of biomolecules with potential therapeutic applications.

    AtıfScopus7OpenAlex7
    ScopusWeb of SciencePubMedİncele
  • MakaleAçık Erişim2024Scopus SJRQ2
    Effects of naringenin on oxidative damage and apoptosis in liver and kidney in rats subjected to chronic mercury chloride

    Kahramanoğullari, Merve; Erişir, Mine; Yaman, Mine; Parlak Ak, Tuba

    Mercury chloride is a type of heavy metal that causes the formation of free radicals, causing hepatotoxicity, nephrotoxicity and apoptosis. In this study, the effects of naringenin on oxidative stress and apoptosis in the liver and kidney of rats exposed to mercury chloride were investigated. In the study, 41 2-month-old male Wistar-Albino rats were divided into five groups. Accordingly, group 1 was set as control group, group 2 as naringenin-100, group 3 as mercury chloride, group 4 as mercury chloride + naringenin-50, and group 5 as mercury chloride + naringenin-100. For the interventions, 1 mL/kg saline was administered to the control, 0.4 mg/kg/day mercury (II) chloride to the mercury chloride groups by i.p., and 50 and 100 mg/kg/day naringenin prepared in corn oil to the naringenin groups by gavage. All the interventions lasted for 20 days. Mercury chloride administration was initiated 1 h following the administration of naringenin. When mercury chloride and the control group were compared, a significant increase in plasma urea, liver and kidney malondialdehyde (MDA) levels, in kidney superoxide dismutase (SOD), glutathione peroxidase (GSH-Px), glutathione-S-transferase (GST) activities (p <.001), and a significant decrease in liver and kidney glutathione (GSH) levels (p <.001), in liver catalase (CAT) activity (p <.01) were observed. In addition, histopathological changes and a significant increase in caspase-3 levels were detected (p <.05). When mercury chloride and treatment groups were compared, the administration of naringenin caused a decrease aspartate transaminase (AST), alanine transaminase (ALT), lactate dehydrogenase (LDH) (p <.01), urea, creatinine levels (p <.001) in plasma, MDA levels in liver and kidney, SOD, GSH-Px, GST activities in kidney (p <.001), and increased GSH levels in liver and kidney. The addition of naringenin-100 increased GSH levels above the control (p <.001). The administration of naringenin was also decreased histopathological changes and caspase-3 levels (p <.05). Accordingly, it was determined that naringenin is protective and therapeutic against mercury chloride-induced oxidative damage and apoptosis in the liver and kidney, and 100 mg/kg naringenin is more effective in preventing histopathological changes and apoptosis.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus13WoS14OpenAlex14
    ScopusWeb of SciencePubMedİncele
  • MakaleYalnız künye2024Scopus SJRQ2
    Molecular characterization of apple endophytic bacteria and biological effect on Alternaria rot on apple

    Bektas, Idris; Yazdıc, Ferit Can; Kusek, Mustafa

    Apple rot disease, caused by Alternaria alternata, is causing significant losses in apple production, especially in post-harvest periods. Alternaria alternata, was isolated from rotten apple fruit of cv Amasya. Identification of the strain isolated from rotten apple fruit was made by ITS sequence and morphological analysis. In the present study, 58 different endophytic bacteria strains were isolated from apple fruit for use in apple rot disease control. Among the isolated strains, 26 endophyte strains were determined to inhibit the radial growth of mycelia of A. alternata in binary culture in PDA media. Based on 16S rRNA sequencing analysis, these antagonistic endophytic bacteria strains were identified as Bacillus ssp. Bacillus methylotrophicus (ib17) showed the highest significant inhibitory effect on the mycelial growth of A. alternata at a rate of 79.5% in PDA medium. The results of in vivo experiments showed that Bacillus licheniformis (ib20) achieved 100% biocontrol when endophyte bacterial strains were inoculated 24 h before the inoculation of A. alternata. When the three bacteria species and A. alternata were inoculated simultaneously, Bacillus myloliquefaciens (ib1), Bacillus licheniformis (ib21) and the Endophytic bacterium (ib16) showed the highest biocontrol efficacy against A. alternata at 81.8%. Furthermore, when the bacterial strains were inoculated at 24 h after inoculation of A. alternata, B. licheniformis (ib21) showed the highest biocontrol efficacy of 83.3% against the fungal pathogen compared to the controls. The endophytic bacterial strains produced fungal cell wall hydrolysing enzymes such as chitinase, cellulase, amylase and protease. According to the results of this study, apple endophytic bacteria are potential candidates to control apple decay caused by A. alternata through cell wall hydrolysing enzymes and reduce disease severity. However, the efficacy of the biological control was dependent on the applied time of epiphytic bacterial strains. Further research is needed on the biochemical mechanisms underlying the activity of these bacteria against A. alternata.

    • SDG 2 · Açlığa Son
    AtıfScopus7WoS7OpenAlex9
    ScopusWeb of Scienceİncele
  • MakaleYalnız künye2024Scopus SJRQ3
    Biogenic Silver and Zinc Enhanced MWCNTs: Nano-Decoration, Characterization, and Antimicrobial Effect

    Ünal, İlkay

    In this study, acid-treated multi-walled carbon nanotubes (MWCNTs) were decorated with silver (Ag), zinc (Zn), and Ag@Zn nanoparticles (NPs) synthesized using plant extract for reducing and stabilizing NPs. The nanocomposites were characterized by Scanning electron microscopy (SEM)-energy-dispersive X-ray spectroscopy (EDX), Transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, and Thermogravimetric analysis (TGA). The stability of functionalized MWCNTs (f-MWCNTs) and NP-decorated MWCNTs was visually evaluated for seven days in ethanol. The antimicrobial efficacy against Gram-positive (Staphylococcus aureus), Gram-negative (Pseudomonas aeruginosa, Escherichia coli) bacteria, and fungi (Candida albicans) was determined using the agar well diffusion assay. Results indicated that Ag-MWCNTs and Ag@Zn-MWCNTs nanocomposites exhibited superior antimicrobial activity against P. aeruginosa and C. albicans compared to other tested microorganisms. Conversely, f-MWCNTs and Zn-MWCNTs showed no antimicrobial effects.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus1WoS1OpenAlex1
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2024Scopus SJRQ2
    An evaluation of societal perception of monkeypox in terms of disease anxiety and stress levels: A Turkish sample

    Yeşiltepe, Akgün; Ayşe, Ç.A.L.

    Objective: The purpose of this research was to examine community perception of monkeypox in terms of epidemic anxiety and stress levels. Methods: This research was performed as a descriptive, cross-sectional study. The research was conducted with 1001 individuals between September and December 2022. AMOS 24, JAMOVI, and SPSS version 25 software were employed. The data were collected using a descriptive form, the Epidemic Anxiety Scale, and the Perceived Stress Scale. Results: The mean Epidemic Anxiety Scale score was 52.47 ± 14.52, and the mean Perceived Stress Scale score was 41.88 ± 6.83. Significant positive correlation was determined between the Epidemic Anxiety Scale and the Perceived Stress Scale (r = 0.350, p =.000). A one-unit increase in perceived stress caused a 0.360 increase in epidemic anxiety (ß = 0.360). In addition, having heard of and fearing monkeypox, thinking about its ability to cause an epidemic, and perceived stress emerged as significant predictors of epidemic anxiety. Conclusion: The community was found to exhibit a moderate level of epidemic anxiety and a low level of perceived stress. Epidemic anxiety levels increased in line with perceived stress levels. We recommend that individuals in need receive support by determining epidemic anxiety and perceived stress levels in the community.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus1WoS1OpenAlex1
    ScopusWeb of SciencePubMedİncele
  • MakaleYalnız künye2024Scopus SJRQ1
    Physical and biological characteristics of eco-friendly films added with Cinnamomum zeylanicum extract for packaging materials

    Gürler, Nedim; Ertekin, Özlem

    The effects of Cinnamomum zeylanicum extract (CZE) at different rations (0%, 1%, 3% and 5%) on gelatin (GL)–polyvinyl alcohol (PVA) blend films were evaluated in relation to the structural, tensile strength, physical, antimicrobial and antioxidant properties of the films in this study. The results showed that water barriers of the film samples decreased, but the UV-blocking property increased and became opaque at the highest GLPVA5 film. The tensile strengths of GLPVA, GLPVA1, GLPVA3 and GLPVA5 films were 1.21, 1.78, 1.62 and 1.95 MPa, respectively. The antimicrobial effect of these films was determined against Escherichia coli, Enterococcus faecalis, Salmonella typhimurium and Bacillus cereus according to the parallel stick method. Antioxidant properties of cinnamon extract were investigated using 2,2-diphenyl-1-picryl-hydrazil (DPPH) methods. The % inhibition of DPPH was found to be 82.00. No antibacterial effect was detected for B.cereus and E. faecalis at 0%, 1%, 3% and 5%. While no activity was observed in 0%, 1% and 3% cinnamon, 7.5 and 3.0 mm zones were detected in S. typhimirium and E. coli, respectively, in 5% cinnamon. The results suggest that the film samples could be used in a potential packaging with antioxidant and antibacterial properties.

    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus9WoS9OpenAlex7
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2024Scopus SJRQ1
    Changes in quality characteristics and inactivation of Salmonella in cake, including oleogel used as a fat replacer, baked with two different methods

    Ozdemir-Orhan, Necla; Eroglu, Zeynep; Omac, Basri

    This is the first study to assess the impact of substitution of shortening (50%) with sunflower-beeswax oleogel in cake formulations on the inactivation kinetics of Salmonella spp. and the quality attributes of cakes baked in conventional (CO) and microwave (MWO) ovens. Four distinct cake samples were examined in the study: Cake samples containing oleogel prepared in two different ovens (Oleo-Cake-CO and Oleo-Cake-MWO) and control cake samples baked in two different ovens (Cont-Cake-CO and Cont-Cake-MWO). The control-batter and oleogel-batter demonstrated shear thinning behavior (pseudoplastic, n < 1), with a good fit to the Power Law model, but viscosity and viscoelastic moduli decreased when the oleogel was used in place of shortening in cake recipes. In addition, the Cont-Cake-MWO had the greatest special volume value (2.31 ± 0.04 mL/g), whereas the Oleo-Cake-CO had the lowest (1.65 ± 0.02 mL/g) (p < 0.05). Furthermore, compared to the samples baked with CO, lower water activity and moisture values (p < 0.05) were observed in the samples baked in MWO due to their higher cooking loss values (p < 0.05). In all baking techniques, the addition of oleogel to the cake formula, used as a fat substitute, resulted in higher values for cohesiveness, hardness, springiness, and chewiness (p < 0.05). As a result, the inactivation of Salmonella in cakes slightly reduced with using oleogel as a fat substitute (p > 0.05), whereas it affected some quality properties of cakes baked with both heat treatments.

    • SDG 2 · Açlığa Son
    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus4WoS4OpenAlex5
    ScopusWeb of SciencePubMedİncele
  • MakaleAçık Erişim2024Scopus SJRQ3
    Synthesis process, thermal and electrical behaviors of Ti3C2Tx MXene; [Syntheseprozess, thermisches und elektrisches Verhalten von Ti3C2Tx MXene]

    Demirelli, K.; Çelik, A.; Aksoy, Y.; Yegin, M.; Barım, E.; Hanay, Ö.; Hasar, H.

    Synthesis of two-dimensional (2D) titanium carbide (Ti3C2Tx), with the name of MXene, by etching Ti3AlC2 (MAX) for different times 20 (v/v) % hydrofluoric acid (HF) at 40 °C was carried out. The influences of time, temperature and source of MAX on the synthesis of MXene were researched. The MXenes produced were characterized by fourier-transform ınfrared (FT-IR) spectroscopy technique, energy dispersive x-ray spectroscopy (EDX), scanning electron microscopy (SEM), x-ray diffraction (XRD) and thermogravimetry (TG) instruments. Above 390 °C, MXene layers were considerably oxidizing and forming anatase and rutile phases of TiO2 under air atmosphere. The resistance of MAX and MXene was 3.6 Ω and 116 Ω, respectively. However, the resistance of the residual part of MXene heated to 620 °C considerably increased to 17850 Ω. This behavior is another important piece of evidence showing that the MXene crystal structure has changed significantly and transformed into a new chemical structure containing anatase and rutil titanium oxide (TiO2). The dielectric loss (ϵ’’) and alternating conductivity (δac) of the MAX and MXenes were determined from their impedance measurements. The ϵ’’ and δac values of MXene were compared with those of MAX. Direct curent conductivities of MAX and MXene produced for 24 h were found to be 0.016 S/cm and 0.0023 S/cm, respectively.

    AtıfScopus12OpenAlex11
    Scopusİncele
  • MakaleYalnız künye2024Scopus SJRQ3
    The RSM-CCD Optimization of Fenton Process for Industrial Wastewater Treatment and Determination of Treatment Efficiency Using Some Biochemical Responses in Dreissena polymorpha

    Tanyol, Mehtap; Serdar, Osman; Ketenalp, Zozan; Yildirim, Nuran Cikcikoglu; Erguven, Gokhan Onder; Yildirim, Numan

    The study investigated antioxidant biomarkers in Dreissena polymorpha to evaluate the efficiency of Fenton process (FP) in Organized Industrial Zone Wastewater (OIZW) treatment. Antioxidant enzymatic activities, including superoxide dismutase (SOD) and catalase (CAT), glutathione peroxidase (GPX), non-enzymatic antioxidants (GSH) and the indicator of lipid peroxidation (TBARS) were measured in D. polymorpha in response to treated OIZW by FP. The performance of the FP has been optimized with response surface methodology (RSM). The optimum conditions (reaction time, and H2O2 and Fe2+ concentration) for OIZW by the FP process were determined. The results showed that the highest COD removal efficiency (83.94 %) was obtained when as Fe2+ concentration=402.35 mg/L, H2O2 concentration=4100.30 mg/L, and reaction time=10.10 min (desirability=1.000). SOD and CAT enzyme was decreased in the 1/25 diluted OIZW group compared to control group. CAT and SOD enzyme activities were increased after treatment compared to control groups. No statistically significant changes were observed in GSH levels and GPx activities. TBARS levels were increased 1/25 diluted OIZW exposure groups compared to the control group. TBARS levels were decreased after treatment. The results revealed that antioxidant parameters are useful biomarkers for determining the treatment efficiency of the FP.

    • SDG 6 · Temiz Su ve Sanitasyon
    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus2WoS1OpenAlex2
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2024Scopus SJRQ2
    Development of rare earth element and carbon fiber-based filler for polyethylene—Mechanical and thermal performance

    Kısmet, Yılmaz; Ayikurt, Pamuk

    In the present study, three fillers produced with carbon fiber powder (CFP) and rare earth elements were developed for low-density polyethylene production. These fillers included CFP with a grain size of less than 400 microns and over 90% pure lanthanum and cerium oxides. Polyethylene was employed to ensure the thermoplasticity and homogeneity of the fillers. The fillers were mixed with the matrix material separately, first mechanically and then homogenously in the extruder, then the test bars were produced with an injection machine. In the mechanical tests, it was determined that the tensile strength of the test bars improved by ~20% and the elastic region increased due to the increasing amount of filler. Similarly, an improvement of about 40% in bending stress was realized. In addition, as the fluidity of the mixtures has improved, it has been possible to produce at lower temperatures and save energy in the production. Thermogravimetric analysis was conducted to determine the melting/crystallization temperatures and material losses in the compounds. The scanning electron microscope analysis showed that the fillers were irregularly distributed on the surface in parallel and perpendicular directions. In addition, x-ray diffraction and energy dispersive spectroscopy analyses were performed on the surfaces.

    • SDG 9 · Sanayi, Yenilikçilik ve Altyapı
    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus1WoS1OpenAlex1
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2024Scopus SJRQ3
    sThe Bioremediation of Industrial Effluents by Phanerochaete Chrysosporium: The COD, TOC Removal Efficiency and Biochemical Assessment for Dreissena Polymorpha

    Serdar, Osman; Yıldırım, Numan; Onder Erguven, Gokhan; Ketenalp, Zozan; Cikcikoglu Yildirim, Nuran; Durmus, Barbaros

    Bioremediation is one of the cheapest and easy method for biological treatment for most kind of industial wastewater. Bioremediation potential of the Phanerochaete chrysosporium for industrial wastewater from Industrial Zone Wastewater plant in Mardin, Turkey, was evaluated. The chemical oxygen demand (COD) and total organic carbon (TOC) reduction efficiencies of P. chrysoporium of on wastewater studied using biomarkers such as catalase (CAT), superoxide dismutase (SOD), glutathione peroxidase (GPx), Thiobarbituric Acid (TBARS) and reduced glutathione (GSH) levels in Dreissena polymorpha. The level of TBARS, a marker of lipid peroxidation was found to be high because of wastewater exposure after treatment. TBARS levels decreased (from 20.2 to 31.6 and from 20.8 to 37.5). GSH levels (from 52.3 to 15.9), CAT levels (from, 119.7 to 15.3 and from 91.1 to 13.4) SOD levels (from 3.8 to 0.9 and from 3.4 to 1.2) and GPX activity (from 177.2 to 104.4 and 174.2 to 100.5) decreased in the wastewater exposure groups during 24 and 96th hour compared to the control groups. GSH levels, CAT, SOD and GPX activity increased after treatment by P. chrysosporium. Results indicate that industrial wastewater caused oxidative stress in Dreissena polymorpha. The findings revealed that the highest removal efficiency for COD and TOC, at 86.3 % and 80.3 % respectively, occurred in the 1/20 diluted medium. P. chrysosporium has proven to be effective in the bioremediation of wastewater from the Industrial Zone Changes in biochemical parameters before and after bioremediation showed that antioxidant parameters such as CAT, SOD, GPx activities and GSH and TBARS levels can be used as biomarker to evaluate bioremediation efficiency.

    • SDG 6 · Temiz Su ve Sanitasyon
    • SDG 12 · Sorumlu Üretim ve Tüketim
    AtıfScopus4WoS2OpenAlex4
    ScopusWeb of Scienceİncele
  • MakaleAçık Erişim2024Scopus SJRQ3
    Structural, Dielectric, and Electrical Properties of Chitosan Composites Doped with Silver for Electrochemical Applications

    Ayhan, Nagihan Karaaslan; Torgut, Gulben

    In this study, chitosan-silver (Chs-Ag) composites containing Ag in different concentrations (0.01–0.08 M) were prepared. The characterization and structure studies of the composites containing 0.01, 0.02, 0.04, and 0.08 M Ag were carried out, and then the dielectric properties of these composites were examined. The composites were characterized by Fourier transform infrared spectrophotometer (FTIR), scanning electron microscopy and energy dispersive spectroscopy (SEM-EDS), and thermogravimetric analysis (TGA). The dielectric and electrical properties of these composites were investigated depending on the frequency at room temperature, and these properties were determined using an impedance analyzer. Spectroscopy revealed that the dielectric constant (ε′), dielectric loss (ε′′), and real (Z′) and imaginary (Z″) components of impedance are found to decrease with increased frequency for both Chs and Chs-Ag (0.01M–0.08 M) composites. On the contrary, the AC conductivity (σac) of samples increased with increasing frequency. ε′ and ε′′ values of Chs were lower than when the Ag was added. The AC conductivity was improved by the addition of silver particles. The results show that the dielectric and electrical properties of Chs-Ag samples were improved by using Ag as filler.

    AtıfScopus3WoS3OpenAlex4
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  • MakaleYalnız künye2024Scopus SJRQ3
    Analyzing the Chemical Constituents and In Vitro Biological Effects of Extracts Artemisia absinthium L. Extracts Obtained Using Different Methodologies and Solvents

    Yagi, Sakina; Zengin, Gokhan; Ibrahime Sinan, Kouadio; Yavuz Paksoy, Mehmet; Cziáky, Zoltán; Jekő, József; Dall'Acqua, Stefano

    The present study aimed to investigate the chemical constituents of different extracts from aerial parts of A. absinthium and to evaluate their antioxidant and enzyme inhibition activity. Extracts were prepared by maceration, infusion or Soxhlet techniques. Results showed that the highest total phenolic and flavonoids contents was recorded respectively from the hexane extract prepared by maceration and ethyl acetate extract obtained by Soxhlet method. The characteristic compounds of Artemisia species artemetin, casticin, sesartemin and yangambin in addition to coumarins were identified in all extracts. Aqueous extract obtained by infusion exerted the highest radical scavenging and ions reducing properties while that prepared by maceration displayed the highest chelating power. Methanol extracts obtained by the two methods of extraction exerted the highest anti-Tyr activity while that obtained by maceration showed the best α-glucosidase inhibition activity. These findings indicated that A. absinthium is a rich source of bioactive molecules with possible therapeutic applications.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus2OpenAlex3
    ScopusWeb of SciencePubMedİncele
  • MakaleYalnız künye2023Scopus SJRQ1
    Improving dielectric properties, electrical conductivity, and thermal properties of biodegradable polymer composites prepared with lanthanum

    Torgut, Gulben; Ayhan, Nagihan Karaaslan; Acikses, Aslisah

    The precipitation method was adapted to synthesize the poly(ε-caprolactone-copolymer- ethylene oxide) (ε-CL-co-EO) composite with the salt of lanthanum (La), a rare earth element. This salt was incorporated into the polymer of different weight percentages to study how it affects the thermal and dielectric properties of the polymer. The resulting products were characterized by Fourier Transform Infrared Spectroscopy, X-ray diffractometry (XRD), Scanning electron microscopy (SEM) and thermogravimetric analysis. XRD and SEM data show that the polymer mixes homogeneously with the metal salt. Thermal degradation data show that the thermal stability of composites synthesized with La is lower than that of pure polymer. The dielectric properties and A.C conductivity measurements of the composites were investigated by using impedance analyzer in the frequency range (100 Hz to 20 kHz) at room temperature. The electrical property results of (ε-CL-co-EO)/La composites displayed that dielectric constant (έ), dielectric loss (ε"), tan delta (tan δ) and A.C electrical conductivity (σac) increase with increasing La content. The largest conductivity of (ε-CL-co-EO)/La composite filled with 20 wt% La was 8.80 × 10−8 S/cm, which was 162% times pure (ε-CL-co-EO). In addition, impedance (IZI) of composites was evaluated from the dielectric data. This procedure is eco-friendly and easy to handle, which provides a promising route to polymer composites in the application of the conductivity field.

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  • MakaleYalnız künye2023Scopus SJRQ2
    Development of chitosan/gelatin/starch composite edible films incorporated with pineapple peel extract and aloe vera gel: Mechanical, physical, antibacterial, antioxidant, and sensorial analysis

    Gürler, Nedim

    In this study, chitosan (C)/gelatin(G)/starch(S) composites incorporated pineapple peel extract (PPE) and aloe vera gel (AVG) were prepared by the casting method as antioxidant agents. Mechanical, water vapor permeability (WVP), moisture content, solubility, opacity, and color properties of the effects of PPE and AVG at different concentrations (0%, 10%, and 30%) were investigated. The prepared films were characterized by Fourier transform infrared spectroscopy in attenuated total reflection (ATR-FTIR), X-ray diffraction (XRD), Thermal gravimetric analysis (TGA), Scanning electron microscope (SEM), mechanical, water barrier, opacity, and color. PPE and AVG extract incorporated edible films improved thermal stability of edible films. Tensile strength decreased with the addition of extracts; the maximum tensile strength was 8.15 MPa for CGS film. The WVP of the films increased with the increasing PPE and AVG concentration. As a biological activity, the films inhibited the growth of gram-positive (Staphylococcus aureus) and gram-negative bacteria (Escherichia coli). With the addition of PPE and AVG to the CGS film, its antioxidant properties were enhanced. In addition, the prepared films were applied for strawberry coating both in the refrigerator and at room temperature. Consequently, these edible-coated films can be used for active food packaging/coating to extend the shelf life of fruits.

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  • MakaleYalnız künye2023Scopus SJRQ2
    Effect of auto-exhaust pollution on leaf anatomy and micromorphology of Pistacia vera L.

    Açar, Mikail

    One of the important causes of air pollution is automobile emissions Automobile exhausts can be toxic and harmful to plants. In light of this, this study aimed to examine the anatomical and micromorphological effects of auto exhaust pollution on Pistacia vera L. (Pistachio), an important agricultural plant. Pistachio leaflet samples taken from heavy traffic areas and rural areas were compared anatomically and micromorphologically. Also, the data were statistically evaluated. As a result of the study, it was seen that there are anatomical and micromorphological differences between the plant in the rural area and the plant in the heavy traffic area in the city center where air pollution and the number of cars are high. In particular, significant differences were detected in the epidermis surface and cuticle structure, trichome cover, stomatal characteristics, as well as mesophyll width, and epidermis anticlinal outer wall width. As a result, the study revealed that the agriculturally important P. vera is affected by pollution anatomically and micromorphologically.

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